Tirage au charbon : le noir le plus permanent, sans le dichromate

The carbon print is a pigment process: a gelatin loaded with carbon pigment is sensitized, exposed under a negative, then developed in warm water. Where light struck, the gelatin hardens and holds the pigment; elsewhere it dissolves. The result is the deepest and most permanent black in all of photography — a print that does not fade. Its weak point lies in what sensitizes the gelatin: dichromate, a carcinogen.
From Poitevin to Fresson: the most durable process
The principle was set by Alphonse Poitevin in 1855; Joseph Swan perfected it in 1864 with transfer. In the 1860s–70s, Adolphe Braun industrialized it — up to 1,500 carbon prints a day — to reproduce masterpieces with unrivalled permanence. And the Fresson family still carries on a direct variant today, the "satin carbon", in its studio — living proof that the process never stopped being desirable.


Braun's carbon (c. 1865, dichromate) and today's Vision Picturale carbon: the same pigment-based, permanent black, without the CMR salt.
The masters of carbon
Carbon is the process of permanence: inventors, industrialists and studios have followed one another without a break. All are in the Maison Picturale library.
From the inventor to the still-living studio — each name links to their prints.
The truth: the sensitizing dichromate
The carbon pigment itself is perfectly inert — one of the most stable there is. The problem is the potassium bichromate (dichromate) that makes the gelatin light-sensitive: the hexavalent chromium it contains is a proven carcinogen and mutagen (CMR), toxic by inhalation. That, and only that, is what must be replaced.
Vision Picturale carbon: archival black, without dichromate
Vision Picturale carbon keeps everything: the pigment, the gelatin (N°05), the water development, and above all that deep black that lasts centuries. Only the sensitizing changes — our N°03 contains no dichromate.
Museum black, without the poison
The most permanent print in photography, in its dichromate-free version. Same pigment, same gelatin, same archival black — no CMR salt.
- Pigment
- Carbon — deep archival black
- Gelatin
- VP N°05
- Sensitizer
- VP N°03 — dichromate-free
- Permanence
- The most stable of processes

The matter, in pictures
Vision Picturale carbon in a few prints and pigment-black details.
FAQ
Is carbon really the most permanent print?
Yes: the image is made of carbon pigment, chemically inert, in gelatin. With no silver or dye to degrade, a well-washed carbon print lasts centuries.
Does VP carbon give the same black as classic carbon?
Yes: same pigment, same gelatin, same development. Only the sensitizer (N°03, dichromate-free) replaces the bichromate.
How does it relate to the Fresson process?
Fresson is a direct variant of carbon, carried on in a studio. Vision Picturale carbon belongs to the same pigment family — in a dichromate-free version you can practise at home.
For the full panorama of non-toxic processes, see our guide to alternative processes or the glossary.


