Gomme bichromatée : le procédé des pictorialistes, sans le dichromate

Gum bichromate is a pigment-based photographic printing process: you mix a pigment, gum arabic and a light-sensitive salt, brush it on, expose it under a negative, then develop in water. The result — velvety matte surface, pigment grain, a painter's touch — made it the weapon of the Pictorialists in the late 19th century. Its only flaw fits in one word: the salt used, dichromate, is carcinogenic.
A process invented in 1855, revealed by Demachy
The principle — bichromated gum hardens in light — was established by Alphonse Poitevin in 1855. It stayed marginal until the 1890s, when Robert Demachy, in Paris, turned it into a genuine artistic medium. In 1895 his first gum prints, shown in Paris, London and Brussels, were received as a revolution: at last a photograph that looked like a drawing, where the hand intervenes. Demachy became its "apostle".


Two monochrome gum bichromate prints a century apart: same matte surface, same pigment grain, radically safer chemistry. We don't recreate Demachy's image — we carry on his process.
The masters who carried it
Gum bichromate is not a laboratory curiosity: it was the process of a whole generation of artist-photographers. Almost every Pictorialist master practised it — and all of them are in the Maison Picturale library.
From the inventor to the great Pictorialists — each name links to their prints.
- Alphonse PoitevinInventor of the process (1855).Voir ses tirages →
- Robert Demachy"Apostle of gum", Photo-Club de Paris.Voir ses tirages →
- Constant PuyoDemachy's peer, French Pictorialism.Voir ses tirages →
- Gustave Le GrayVoir ses tirages →
- Alfred StieglitzPhoto-Secession, New York.Voir ses tirages →
- Heinrich KühnGum and gum-platinum.Voir ses tirages →
- Gertrude KäsebierVoir ses tirages →
- Frank EugeneVoir ses tirages →
- Clarence H. WhiteVoir ses tirages →
- F. Holland DayVoir ses tirages →
- Charles MarvilleVoir ses tirages →
- Théodore-Henri FressonWhose studio carries on carbon-gum.Voir ses tirages →
Gum, by those who made it
A few period prints, monochrome and sanguine, from the masters' archive. Each links to its page in the Maison Picturale library.
Voir le maître →
Voir le maître →
Voir le maître →
Voir le maître →
Voir le maître →
Voir le maître →
Historical gum bichromate prints (public domain). Click to enlarge.
The truth: dichromate
What makes historical gum problematic is neither the pigment nor the gum arabic — it is the potassium or ammonium bichromate (dichromate) that makes it light-sensitive. The hexavalent chromium it contains is a proven carcinogen and mutagen (CMR), toxic by inhalation and a skin sensitizer. You can admire the genius of the process without wanting to handle that salt at home.
Aquaprint: gum, reformulated without dichromate
Aquaprint is our reformulation of gum bichromate. The gesture, the gum arabic, the pigment, the water development, the look: all preserved. Only the sensitizer changes — our N°03 contains no dichromate. Same Pictorialist beauty, practised safely, at home.
Gum, without the poison
Same process, same look, different chemistry. Aquaprint lets you practise gum bichromate — including in sanguine, like Demachy — with no CMR salt at all.
- Sensitizer
- VP N°03 — dichromate-free
- Classification
- No CMR
- Look
- Matte surface, pigment grain, multiple layers
- Practice
- Cotton paper, at home, in daylight

The three Aquaprint gums
Gum bichromate is not a single colour: it is a family. Aquaprint offers three — all with the N°03 sensitizer, dichromate-free.
Sanguine
Sanguine is a precise gum variant: a red-brown pigment evoking the red chalk of Old Master drawings. Demachy made it famous, his red gums recalling Renaissance sanguine drawings. Aquaprint Sanguine follows exactly that path.


Demachy's sanguine (1898) and today's Aquaprint Sanguine: the same red chalk, without the dichromate.
Four-colour
Where Pictorialists mostly stayed monochrome, gum also lends itself to colour: several pigmented passes (cyan, magenta, yellow, black) are stacked. Aquaprint Quadrichromie takes gum all the way to a full colour image — still dichromate-free.
FAQ
Does Aquaprint really give the same look as dichromate gum?
Yes. Dichromate is only a hardening trigger; it plays no part in the final image. The matte surface, the grain and the ability to stack layers are identical.
Can you work in colour, like four-colour gum?
Yes: you superimpose several pigmented passes (cyan, magenta, yellow, black), exactly as in traditional gum — without dichromate.
Is it really safe at home?
The N°03 sensitizer contains no CMR salt. As with any studio practice you work tidily, but without the carcinogenic risk of dichromate.
For the full panorama of non-toxic processes, see our guide to alternative processes or the glossary.


